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Group II vs Group III Base Oils: Performance and Formulation Insights

By Sinopec Online Technical Team

Introduction

Group II and Group III base oils are the backbone of many modern lubricant formulations. Both come from hydroprocessing, yet deeper conversion and isomerisation in Group III change the molecular distribution and deliver higher viscosity index along with very low sulphur.

Processing overview

Group II

  • Hydrocracked and hydrotreated paraffinic stocks.
  • High saturates and very low sulphur by API definition.
  • Dewaxing may be catalytic or solvent based depending on unit design.

Group III

  • Hydrocracked, hydrotreated, and hydroisomerised to shift straight paraffins to iso-paraffins.
  • Very high saturates and near zero sulphur, with naturally higher viscosity index.
  • Catalytic dewaxing and isomerisation improve low temperature behaviour.

Typical property ranges

The values below are indicative ranges used for selection and do not represent a single supplier’s data.

Property Group II Group III
Viscosity index About 95 to 115 About 120 and above
Noack volatility Lower than Group I Lower than Group II for like viscosity grade
Oxidation stability High Very high
Sulphur Very low Near zero
Saturates High Very high
Solvency Moderate Lower than Group II
Cold flow Good Very good for same kinematic viscosity

Test methods that matter

  • Viscosity index: ASTM D2270
  • Volatility: Noack ASTM D5800
  • Oxidation stability: ASTM D943 and bench tests used by additive companies
  • Cold crank behaviour: CCS ASTM D5293 and MRV ASTM D4684 for finished oils
  • Pour point: ASTM D97 or ASTM D5949
  • Saturates and sulphur: Group classification tests used to confirm API group status

Formulation trade-offs

  • Volatility and fuel economy: Group III helps meet low volatility and high VI targets in modern engine oils.
  • Solvency and seal behaviour: Lower solvency in Group III may need additive system adjustment or limited use of higher solvency components.
  • Shear stability: Higher VI can reduce dependence on VI improvers, which supports shear stability in severe duty.
  • Cost versus performance: Blends of Group II and Group III are common to hit specifications at controlled cost.

Applications

  • Passenger car and heavy duty engine oils: Group III supports low volatility and extended oxidation life.
  • Industrial lubricants: Group II is widely used in hydraulic, turbine, compressor and circulation oils where balanced solvency and oxidation control are required.
  • Low temperature service: Group III improves cold flow for winter grades.

Selection framework

  1. Start with performance standards that must be met, such as API, ACEA or OEM specifications.
  2. Choose the base stock that achieves volatility and oxidation targets with the simplest additive treat.
  3. Check low temperature limits and pumpability margins for your climate and duty.
  4. Validate material compatibility and seal performance.
  5. Optimise cost by blending Group II and Group III where appropriate.

Cross-References

Relevant base oil categories

Published by Sinopec Online Technical Team